Water’s Ferroelectricity Demonstrated As Physicists ‘Dissolve’ Water in an Emerald

Scientists detect ferroelectric properties of water molecules by placing them into a network of nanocavities in a crystal

 

Ferroecelctricty is Water

Scientists from the Moscow Institute of Physics and Technology and several research teams working in Russia and other European countries have been the first to reliably realize and document the phenomenon of ferroelectricity in water by confining water molecules within nano-cages in a beryl crystal. The results of their work are published in Nature Communications.

http://www.nature.com/articles/ncomms12842#abstract

In solid-state physics, the notion of ferroelectricity refers to the property of a material whose electric dipole moments, while cooling, align themselves in an ordered pattern. Because the water molecule (H2O) has a very large dipole moment (approx. 1.9 D, where “D” stands for the debye, a unit of electric dipole moment), one would expect that in liquid water the molecular dipoles should strongly interact with each other and, consequently, align themselves in a certain manner, i.e., demonstrate ferroelectric behavior.

However, in liquid water, such ordering does not occur due to the molecules being located so closely that their interactions are dominated by short-range hydrogen bonds, which suppress the long-range dipole-dipole forces.

The situation changes drastically when water molecules interact with foreign structures/surfaces (e.g. hydophilic substances) or are confined within closed cavities of sufficiently small (nanoscale) dimensions. Under such conditions, the role of hydrogen bonds is diminished by “redirecting” them to these additional interactions, so as to make the interactions between water dipoles come to the fore.

The team of researchers devised a subtle and unexpected way of creating conditions when the dipole-dipole interactions between water molecules would be stronger than hydrogen bonding. They managed to confine individual H2O molecules in a network of nano-sized cavities within the crystal structure of beryl, a mineral used as a gemstone–the most famous varieties being emerald and aquamarine. These cavities occur at regular intervals (facilitating mathematical analysis) and, most importantly, are spaced 5-10 Å (angstroms) apart, which means that the hydrogen bonds are negligible (effective interaction range 1-2 Å), while the dipole-dipole interactions (effective interaction range 10-100 Å) still have a significant effect.

Ferroelectricity in WaterMaterials demonstrating ferroelectricity possess several characteristic properties, or “fingerprints,” which enable experimenters to reliably detect dipolar ordering in a system. For instance, the dielectric permittivity of a ferroelectric is known to vary with temperature according to the Curie-Weiss law. Another example is the notion of the “soft mode,” i.e., a special absorption resonance at infrared or terahertz frequencies, whose parameters have a specific dependence on the temperature. The researchers detected all these ferroelectric fingerprints in water “dissolved” in beryl.

“Our team has succeeded in placing water molecules under conditions allowing us to obtain the first-ever reliable observations of the alignment of molecular dipoles of water. As for possible practical applications, their scope could be fairly wide. Researchers now have the opportunity to study this phenomenon under the influence of various external factors–temperature, pressure, the ionic environment, etc., and thus advance our understanding of this phenomenon and its role in various systems, including living organisms,” says Boris Gorshunov, the head of the Terahertz Spectroscopy Laboratory at the Moscow institute of Physics and Technology.

The electric fields generated by nano-confined water could play a vital role in various phenomena studied in biology, chemistry, geology, and meteorology, or even in the formation of the planets of our Solar System.

In fact, many computer calculations and simulations do predict the alignment of water molecular dipoles, provided that hydrogen bonds are somehow “diverted” to “target” the artificially introduced surfaces or cavities such as carbon nano-tubes or two-dimensional metal substrates. However ,despite numerous attempts by researchers worldwide, no firm experimental evidence existed for the dipole-dipole ordering of water.

(this article is adapted from “Physicists ‘Dissolve’ Water in an Emerald” originally published at eurekaalert.com)

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